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Synthesis, spectroscopic and electrochemical characterization of different isomer types in tetrazolatoindium(III) porphyrins

Identifieur interne : 020E38 ( Main/Repository ); précédent : 020E37; suivant : 020E39

Synthesis, spectroscopic and electrochemical characterization of different isomer types in tetrazolatoindium(III) porphyrins

Auteurs : RBID : Pascal:92-0401831

Descripteurs français

Pascal (Inist)
- Métal trivalent Complexe, Coordinat organique, Complexe Mixte, Hétérocycle azote, Macrocycle, Porphyrine métallique, Préparation, Structure moléculaire, Indium III Complexe, Spectre RPE, Spectre UV visible, Spectre RMN, Tétrazole dérivé, Voltammétrie cyclique, Propriété électrochimique, Potentiel demi vague, Résolution temporelle.

English descriptors

KwdEn :
- Complexes Mixed, Cyclic voltammetry, EPR spectrum, Electrochemical properties, Half wave potential, Indium III Complexes, Macrocycle, Metalloporphyrin, Molecular structure, NMR spectrum, Nitrogen heterocycle, Organic ligand, Preparation, Time resolution, Trivalent metal Complexes, Ultraviolet visible spectrum.

Abstract

The synthesis and characterization of nine indium(III) porphyrin complexes with three types of a-bonded tetrazolato axial ligands are reported. The investigated compounds In(por)(N₄CR) where R=CMe₃, CH=CH₂ or CH=CHCN and por=the dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin (oep), 5,10,15,20-tetraphenylporphyrin (tpp) or 5,10,15,20-tetra-p-trifluoromethylphenylporphyrin (tfpp) were characterized by UV/VIS

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Pascal:92-0401831

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Synthesis, spectroscopic and electrochemical characterization of different isomer types in tetrazolatoindium(III) porphyrins</title>
<author><name sortKey="Guilard, R" uniqKey="Guilard R">R. Guilard</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>CNRS Univ. Bourgogne, fac. sci. Gabriel, lab. synthèse electrosynthèse organométalliques</s1>
<s2>21100 Dijon</s2>
<s3>FRA</s3>
<sZ>1 aut., 2 aut., 3 aut., 4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Bourgogne</region>
<settlement type="city">Dijon</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Jagerovic, N" uniqKey="Jagerovic N">N. Jagerovic</name>
</author>
<author><name sortKey="Tabard, A" uniqKey="Tabard A">A. Tabard</name>
</author>
<author><name sortKey="Naillon, C" uniqKey="Naillon C">C. Naillon</name>
</author>
<author><name sortKey="Kadish, K M" uniqKey="Kadish K">K. M. Kadish</name>
</author>
</titleStmt>
<publicationStmt><idno type="inist">92-0401831</idno>
<date when="1992">1992</date>
<idno type="stanalyst">PASCAL 92-0401831 INIST</idno>
<idno type="RBID">Pascal:92-0401831</idno>
<idno type="wicri:Area/Main/Corpus">022715</idno>
<idno type="wicri:Area/Main/Repository">020E38</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">0300-9246</idno>
<title level="j" type="abbreviated">Dalton. trans.</title>
<title level="j" type="main">Dalton transactions</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Complexes Mixed</term>
<term>Cyclic voltammetry</term>
<term>EPR spectrum</term>
<term>Electrochemical properties</term>
<term>Half wave potential</term>
<term>Indium III Complexes</term>
<term>Macrocycle</term>
<term>Metalloporphyrin</term>
<term>Molecular structure</term>
<term>NMR spectrum</term>
<term>Nitrogen heterocycle</term>
<term>Organic ligand</term>
<term>Preparation</term>
<term>Time resolution</term>
<term>Trivalent metal Complexes</term>
<term>Ultraviolet visible spectrum</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Métal trivalent Complexe</term>
<term>Coordinat organique</term>
<term>Complexe Mixte</term>
<term>Hétérocycle azote</term>
<term>Macrocycle</term>
<term>Porphyrine métallique</term>
<term>Préparation</term>
<term>Structure moléculaire</term>
<term>Indium III Complexe</term>
<term>Spectre RPE</term>
<term>Spectre UV visible</term>
<term>Spectre RMN</term>
<term>Tétrazole dérivé</term>
<term>Voltammétrie cyclique</term>
<term>Propriété électrochimique</term>
<term>Potentiel demi vague</term>
<term>Résolution temporelle</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The synthesis and characterization of nine indium(III) porphyrin complexes with three types of a-bonded tetrazolato axial ligands are reported. The investigated compounds In(por)(N<sub>4</sub>
CR) where R=CMe<sub>3</sub>
, CH=CH<sub>2</sub>
 or CH=CHCN and por=the dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin (oep), 5,10,15,20-tetraphenylporphyrin (tpp) or 5,10,15,20-tetra-p-trifluoromethylphenylporphyrin (tfpp) were characterized by UV/VIS</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0300-9246</s0>
</fA01>
<fA02 i1="01"><s0>JCDTBI</s0>
</fA02>
<fA03 i2="1"><s0>Dalton. trans.</s0>
</fA03>
<fA06><s2>12</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Synthesis, spectroscopic and electrochemical characterization of different isomer types in tetrazolatoindium(III) porphyrins</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>GUILARD (R.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>JAGEROVIC (N.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>TABARD (A.)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>NAILLON (C.)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>KADISH (K. M.)</s1>
</fA11>
<fA14 i1="01"><s1>CNRS Univ. Bourgogne, fac. sci. Gabriel, lab. synthèse electrosynthèse organométalliques</s1>
<s2>21100 Dijon</s2>
<s3>FRA</s3>
<sZ>1 aut., 2 aut., 3 aut., 4 aut.</sZ>
</fA14>
<fA20><s1>1957-1966</s1>
</fA20>
<fA21><s1>1992</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA24 i1="01"><s0>eng</s0>
</fA24>
<fA43 i1="01"><s1>INIST</s1>
<s2>130 A</s2>
<s5>354000028886190130</s5>
</fA43>
<fA44><s0>0000</s0>
</fA44>
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</fA45>
<fA47 i1="01" i2="1"><s0>92-0401831</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i2="1"><s0>Dalton transactions</s0>
</fA64>
<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>The synthesis and characterization of nine indium(III) porphyrin complexes with three types of a-bonded tetrazolato axial ligands are reported. The investigated compounds In(por)(N<sub>4</sub>
CR) where R=CMe<sub>3</sub>
, CH=CH<sub>2</sub>
 or CH=CHCN and por=the dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin (oep), 5,10,15,20-tetraphenylporphyrin (tpp) or 5,10,15,20-tetra-p-trifluoromethylphenylporphyrin (tfpp) were characterized by UV/VIS</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C02B04</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Métal trivalent Complexe</s0>
<s2>NC</s2>
<s2>NA</s2>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Trivalent metal Complexes</s0>
<s2>NC</s2>
<s2>NA</s2>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Metal trivalente Complejo</s0>
<s2>NC</s2>
<s2>NA</s2>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Coordinat organique</s0>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Organic ligand</s0>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Ligando orgánico</s0>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Complexe Mixte</s0>
<s2>NA</s2>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Complexes Mixed</s0>
<s2>NA</s2>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Complejo Mixto</s0>
<s2>NA</s2>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Hétérocycle azote</s0>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Nitrogen heterocycle</s0>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Heterociclo nitrógeno</s0>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Macrocycle</s0>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Macrocycle</s0>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Macrociclo</s0>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Porphyrine métallique</s0>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Metalloporphyrin</s0>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Porfirina metálica</s0>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Préparation</s0>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Preparation</s0>
</fC03>
<fC03 i1="07" i2="X" l="GER"><s0>Vorbereitung</s0>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Preparación</s0>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Structure moléculaire</s0>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Molecular structure</s0>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Estructura molecular</s0>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Indium III Complexe</s0>
<s2>NC</s2>
<s2>NA</s2>
<s6>Indium «III» Complexe</s6>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Indium III Complexes</s0>
<s2>NC</s2>
<s2>NA</s2>
<s6>Indium «III» Complexes</s6>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Indio III Complejo</s0>
<s2>NC</s2>
<s2>NA</s2>
<s6>Indio «III» Complejo</s6>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Spectre RPE</s0>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>EPR spectrum</s0>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Espectro RPE</s0>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Spectre UV visible</s0>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Ultraviolet visible spectrum</s0>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Espectro UV visible</s0>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Spectre RMN</s0>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>NMR spectrum</s0>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Espectro de RMN</s0>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Tétrazole dérivé</s0>
<s4>INC</s4>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Voltammétrie cyclique</s0>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Cyclic voltammetry</s0>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Voltametría cíclica</s0>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Propriété électrochimique</s0>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Electrochemical properties</s0>
</fC03>
<fC03 i1="15" i2="X" l="GER"><s0>Elektrochemische Eigenschaft</s0>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Propiedad electroquímica</s0>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Potentiel demi vague</s0>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Half wave potential</s0>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Potencial media onda</s0>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Résolution temporelle</s0>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Time resolution</s0>
</fC03>
<fC03 i1="17" i2="X" l="GER"><s0>Aufloesungsvermoegen zeitlich</s0>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Resolución temporal</s0>
</fC03>
<fN21><s1>243</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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Synthesis, spectroscopic and electrochemical characterization of different isomer types in tetrazolatoindium(III) porphyrins

Synthesis, spectroscopic and electrochemical characterization of different isomer types in tetrazolatoindium(III) porphyrins

Descripteurs français

English descriptors

Abstract

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